This is not possible in the current version of Vizard. Here is some sample code showing how to use the Windows MessageBox function to customize the title:
Code:
import viz
viz.go()
import win32gui
import win32con
# Equivalent to viz.message
win32gui.MessageBox(viz.window.getHandle(),'My Message','My Title',win32con.MB_OK)
# Equivalent to viz.ask
print win32gui.MessageBox(viz.window.getHandle(),'My Question','My Title',win32con.MB_YESNO) == win32con.IDYES